Possible, but probably not a matter of simply switching a .033mfd cap in and out of circuit. In a simple treble-cut tone circuit, the amount of frequency filtering depends on the values of the cap and the pot in combination. One affects the other and is, in this case, called an R-C circuit (Resistance-Capacitance circuit).
You'd need to substitute a fixed value resistor for the tone pot in this circuit...
http://www.bassesbyleo.com/images/g&..._with_tone.jpg
...the value of which would be the same as the pot's resistance at the setting you like. You'd build a circuit consisting of a SPST switch, the resistor (1/4 watt is fine), and the normal .047mfd cap. Connect one lead of the cap to ground and its other lead to one lead of the resistor. Connect the other lead of the resistor to one pole of the switch and the other pole of the switch to the signal hot lead
after both volume pots.
I think that should get you where you want to be. Should. At least conceptually. YMMV.
Ken...