Polarity is only relevant with DC.
The plugs can be wired so that the centre (sometimes called 'tip') is negative or positive. Regarding 2.1mm vs 2.5mm, this is the diameter of the of the pin on the socket & the hole in the centre of the plug. A 2.1mm plug won't fit in a 2.5mm socket. A 2.5mm plug will fit in a 2.1mm socket but won't make a good connection, will wobble around & possibly be intermittent.
95% of DC power-supplied fx use centre negative 2.1mm plugs (Boss possibly started this tradition). Having said that, never assume - confirm your pedal's power supply needs before powering it up.
All irrelevant to you on this occasion because you're talking AC but good to know for the future, right?
p.s. I power my Bass Whammy with a PPAC & the red-plug Voodoo Lab cables & have never had a problem
