I was first looking at DI options at Thomann, there are many inexpensive ones...
...at the end of the day I went to bed believing I need a gong in my life
I know what you mean. Options can get dizzying.
I say I'm not in the market myself, but I have Zoom B2 that's getting really long in the tooth, so I do keep an eye out for my next move, and I can't say for sure what I'd get if push came to shove right now. I can vacillate, sometimes valuing simplicity and at other times being attracted to bells and whistles.
I have some varied uses for my pedal from sometimes being nothing more than a tuner where a sound engineer has a preferred DI that they want to use to being my DI with amp and cabinet sims if I'm playing a duo or trio gig and everyone is running direct to PA. While I only use a fraction of what it's capable of, I've found the staple things that I use, with most gigs (and for IEM rehearsals) I use the Sansamp DI model to EQ so my IEM mix isn't so thin as it might be with a straight DI, and that makes it worthwhile for me.
At least starting out, you're looking to gear up for a single playing situation and the world's your oyster. One thing you might do is try to settle on what suits you best on a scale of simplicity. Would you prefer to not have this be something you have to do much messing with? A zero knobs option is as far as you can go in that direction. Would you like to have tools at your fingertips and if so, how deep into that do you want to go? With a preamp/multi-fx/amp modeling pedal, you can find a sound you like made possible by the pedal and leave the rest untapped or you can go all the way into setting up patches for different songs with different amp models and effects. That comes at a cost of the time you have to spend learning.
If I were in your position, I'd pass on the idea of plugging directly into the mixer. If I were more inclined toward keeping things simple, I'd get a DI box to have a signal with a proper level going to the mixer, but not totally cheap out on some unknown. If I were more inclined toward wanting EQ and some other features (which I personally am) even if just for the fun of it but also trying to keep the cost down, I'd round up the options that fit price-wise and and try to make the best feature comparison I could, looking to youtube and online reviews.
Edit: also if I were in your position, I would be totally geeking out on that mixer. You really have something that most people would love in a rehearsal room. All those input channels, 14 monitor channels, multi-track recording by connecting a drive, and on and on. Anyway, I noticed that 4 of the monitor outs (aux) have a pair of TRS (1/4" stereo plug) that can drive IEM/headphones, so two people don't actually need headphone amps.