Mixing impedances with similar cabs isn't advisable, as they will receive unequal amounts of power from the amplifier.
That said, what you're trying to do isn't that feesable. To do this you would need to re-wire the internal cab to 16 ohms (not possible to wire it as 8ohms), and then add your 8ohm cab. Leaving you running at around 5 ohms.
In my personal opinion what you're aiming to do isn't really worth doing. Certain combos run at 8 ohms, and can have another 8 ohm cab added to them. Yours isn't one of them. If you're short on volume, I would suggest using a different setup. You could try and trade your combo for it's equivalent in head and cab, but making sure you have an 8ohm cab. Then you would be able to add another 8 ohm cab.
Oh, and finally: I've been on talkbass for about 3 years now, and I must say that threads similar to your question come up on an almost daily basis. Questions such as "How if at all, can i add another cab? " are Frequently Asked, and such come under "FAQ"!