I have had problems getting solder to stick to the back of pots. Will using flux help?
It will help, but IMO you need to lightly sand the plating for the best adhesion.
Have always used flux even with Ersin multi core solder; for general work I've been using LACO regular soldering flux but would appreciate advice as to if this is the best brand for general electronics soldering.
BTW, the work I've seen for both standard MIL-SPEC as well as nuclear submarine appications call out for flux and then flux removal after the jobs done.