This will work for whatever volume the B25C can provide, which is probably not much.
There are a couple of potential issues:
1. Mixing amps and cabs can result in polarity, phase, and group delay issues that degrade the sound. If the two rigs are out of polarity the low end will cancel. If the phase and group delay vary too much, it degrades sound quality and and can produce sort of a hollow effect where the sound is obviously louder but simultaneously harder to hear when playing with others.
2. Cutting the Bass control may help, but it's not ideal. The reason is because Bass controls tend to reach up pretty high into the mids, so it winds up cutting some of the most important frequencies. If this occurs, a variable HPF should work better, but off course add cost. My guess is the best results will be with the HPF up around 150hz.
The FDeck HPF can be adjusted up to 140hz. The Broughton can be adjusted up to 190hz.
Try elevating and tilting the Ampeg...without the extra Acoustic combo.
That looks like an RB combo, but I don't know which one it is. It would be helpful to know.
The RB115 and RB210 can run an 8 ohm extension cab. AFAIK they don't make RB exention cabs. The PF cabs have very similar cosmetics, but I don't know how well they would match with the RB Comb speakers. If they are a perfect match, you would get ~6dB of additional headroom, which is quite a bit.