...I looked at the two pots solely as two volume pots
I almost did, too LOL
Btw, the neck pickup is 25k and the bridge pickup 7k...
Just curious, are the volumes of the two pickups about equal?
Would that still be the case if the tone pot is at 10? maybe a 'no load tone pot' would be even better...
Unfortunately, no. That's due to it's location electrically between the Brdg PU and Brdg Vol pot. Maybe the following will show why.
I took your diagram and schematicised it to show how it electrically works. Unfortunately, the Bridge Vol pot is the only spot in the circuit to keep the Brdg Tone control from draining high freqs from the neck output. (but there are two workarounds mentioned later).
Notice in the full circuit, when the Brdg Vol pot is at 10 (as shown), the wiper (arrow) is connected to the top of the pot. It's now like a straight wire connected there. Neck Vol pot output (top of pot) is now directly connected to the Brdg Tone control, which is happily removing high freqs from both outputs.
The inset shows the 'dialed back' resistance of the Brdg Vol, blocking the neck high freqs from touching the Brdge Tone control. Players are aware of 'dialing back' a volume pot to keep the tone isolation. One either accepts this in 2 vol/2 tone passive configs, or not. Yours is similar, so the same level of acceptance choice applies.:
But, here's a workaround. Add a fixed resistor after the Brdg Vol output as shown in the next schematic. Neck output is not affected by this. 25kΩ (1/10 of a 250kΩ linear pot or 1/20 of a 500k linear pot) as starting point. The
resistor is a permanent isolation solution, even when Brdg Vol is at 10.
25kΩ is only a starting point as value needs to be adjusted depending on how much isolation you want. Higher value = better isolation. Unfortunately the resistor drops the Brdg volume a little. Higher value = less volume from Brdg.:
There's a 2nd workaround that definitely gives you complete isolation, but it requires a battery and a small (about 1/2 size of battery) dual channel buffer preamp. Here's one from Bartolini. I have the single channel version in one bass and can recommend it for transparency. Other manufacturers make a similar item.:
Adjustable Gain Buffer - AGB & AGDB - Bartolini Pickups & Electronics
That's all I got for choices for your circuit. Others smarter and more experienced than me might have a solution we both could learn from to keep the tone control isolation you want.