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Gain vs volume vs bass (or low)

I bought a new combo amp (acoustic 115) and my question is when I'm turning it up to get louder, are you supposed to turn up the gain and volume in equal parts or turn the gain way up and the volume a little or vise versa? Turning up the bass works to but I'm asking because I don't want to damage anything and honestly I don't get why there is a gain and volume and not just a volume. Thanks for shedding some light on the situation for me :-)
 
"Gain" is the volume going INTO the amp. This allows you to get more distortion, or less. "Master" is the volume coming OUT OF the amp. This allows you to crank the Gain as high as you want, but still turn down the volume, if you want a driven sound but not so loud.