No, I haven't used them together and I'm not sure I would as they are a bit redundant. I suppose you could setup the TH500 for a clean tone, and then the the TH pedal as a stompbox for turning on overdrive or something. But I'd use the Agro pedal for that personally.
One cool trick I also like to use on the TH (pedal or amp) combined with those settings is to just use the mid frequency knob to adjust articulation. If you turn the knob counter clockwise, it allows more upper mids in the tone while cutting mids and low mids which brings out more articulation. If you dial it clockwise it cuts upper mids while boosting lower mids back up which makes the tone fatter.
One cool trick I also like to use on the TH (pedal or amp) combined with those settings is to just use the mid frequency knob to adjust articulation. If you turn the knob counter clockwise, it allows more upper mids in the tone while cutting mids and low mids which brings out more articulation. If you dial it clockwise it cuts upper mids while boosting lower mids back up which makes the tone fatter.
