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No effects experience.

I say don't bother with multi-effects. They sound like crap IMO.

Other than that, what has been suggested is what I would say. I love effects and integrate them a lot into what I play. I also haven't bought anything new in probably a year or two now. The staples of my setup are OD, Fuzz, wah, octave, chorus, and filter. You will probably need to search around a bit to find pedals you like. I use:

Ibanez TS-5 for overdrive
EHX Little Big Muff for Fuzz
Dunlop 105Q for wah
EHX POG for octave
BOSS CH-1 for chorus
EHX Q-Tron for filter

I like all of these pedals a lot, but you might not. Check them out if you get a chance though. You would benefit most from overdrive, distortion, or fuzz, most likely.