Billy – series connecting two 8 ohm cabs will present a 16 ohm impedance to the amp. If the cabs are grossly different, they will not necessarily sound the same as used alone, as the series connection results in some interaction. Is you amp unable to drive 4 ohms? That’s what you’ll get if you wire them in parallel. This will make considerably more power available to the speakers while eliminating any concerns of interaction.
MyKroberts – For maximum volume, try to get a cab rated at 4 ohms. This will pull more power from the amp than 8 ohms, and all things equal, will end up a little louder. I say all things equal, because cab efficiency and tonal characteristics will have as much or more to do with volume than the incremental difference in power. You are likely to get better efficiency with cabs with more speakers (410s generally have higher efficiency than 210s, which generally have higher efficiency than 115s), but there are plenty of exceptions. That said, I’d always go for tone first.
How this all works mathematically is covered extensively in this thread.