I guess this is a synthetic core string, probably with a PEEK core.
These core stretches a lot under tension which means that there will be very small gaps between the windings. When these gaps move over the core some gaps close and others get bigger. It does not necessarily lead to a higher danger of breaking, but the mass of the string is unevenly distributed and therefor the partials of the string get out of tune.
If the string still sounds OK for you, you can continue playing it, but the risk of the edges of the metal windings cutting into the synthetic fibers is higher than with the micro gaps only.
So better take a replacement string with you if you keep playing this string.
BTW, I would call that "windings are separating" not "unwinding", since unwinding in my opinion means that the winding broke and both ends unwind from the core because of that.
That kind of unwinding on the playing part of the string is not repairable. On the underlength or the pegbox part you might be able to put some silicon tube or electronics shrinking tube (not with synthetic windings or core) over that part to stop the unwinding.