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Double Bass spirocores prone to breaking?

I've fairly recently switched to spirocores after a decade of using hybrid 'gut-like' strings (mainly innovations, sometimes animas), and in the 6 months or so since I switched have twice had strings break on me during a gig. This never happened before I switched. Unlucky coincidence, or are spiros more prone to breaking?

I play with pretty high strings, and play a lot of free improv as well as jazz so they get some fairly heavy use...
 
I broke one 3/4 Mittel E at the nut that was on an EUB I bought used. It semed like the strings were old and the string might have been clamped between the other windings and the headstock. It happend during tuning up the string. Looked a bit like corrosion too, but not too much. Since I made a new nut and used other strings now I cannot check out if the reason might have been a tight nut groove.

I never had problems with my over 20 year old Spirocore Mittel 4/4 and put them down about two years ago only to try something else. They are still in my string drawer and bow very well now for a Spirocore.
 
I would check the bridge slots. Are they rounded enough so that there is no sharp angle for the string at the bridge? What is your string angle (vibrating part to underlength) at the bridge?
I think Innovation Braided or Honeys are a bit thinner than Spiros at the A and E, so the slots may be a little bit too narrow.

But even then, I wonder that this happened with Spiros during the first six months.
I would contact Thomastik customer support for getting replacements and also for informing them under which conditions this had happened. I'm sure they would like to know that and check if something happened in the manufacturing process.

I think Spirocores have one of the most robust strings cores on the market (but Innovation string cores are also very reliable). Generally I would try to do things with Spiros, that I wouldn't try with most other strings.
 
Yes, spiros are virtually indestructible. But the one (rookie) mistake that will almost always break any E-string especially is if you pinch the winding against the cheek of the peg box. That's because the thicker string has troubles doubling back upon itself, binds, and then breaks.