I've been worried about this for a while. What is actually happening in terms of physics & chemistry (you know proper scientific stuff, not voodoo and superstition) when strings lose their zing? I mean, the sound generated is from a metal wire oscillating within a magnetic field so what happens when a string ages? I can see some physical degradation over time as the string stretches, loses some elasticity, so maybe the oscillations are damped faster, which could give rise to less of the higher frequencies of oscillation, and this could give rise to a duller tone with loss of top end sparkle.
I can also see some oxidation of the metal over time with the slightly acid pH of skin + sweat (about pH 4.5 - 5) but this is hardly going to have an effect on oscillations is it? If not, then these longer lasting strings with molecular coatings on them shouldn't make any difference to the retension of a good lively tonal response and we're having the wool pulled over our eyes by some technical misconcept.
What's really happening when strings start to lose their tone?
I can also see some oxidation of the metal over time with the slightly acid pH of skin + sweat (about pH 4.5 - 5) but this is hardly going to have an effect on oscillations is it? If not, then these longer lasting strings with molecular coatings on them shouldn't make any difference to the retension of a good lively tonal response and we're having the wool pulled over our eyes by some technical misconcept.
What's really happening when strings start to lose their tone?