As an apprentice I was taught :-
Always keep a tidy working area to help minimise accidents.
if you are going to use a tool of any sort, hand or power, always take the correct stance first. e.g. Feet slightly apart, one forward of the other for stability.
If you think to yourself 'I shouldn't be doing this because .....' Stop immediately before ..... happens. Like when you are using a screwdriver and your other hand is where it will be pierced if it slips.
Don't wear loose clothing that could get caught in power tools.
Remove any watches or jewellery that could get caught up.
Tie back long hair when using power tools. Not a problem for me now but as an apprentice we were issued with hair nets. Very uncool.
Don't use damaged tools, e.g. files with cracked handles, chisels with a 'mushroom head' and only use tools for their intended purpose.
There are probably a lot more but it was a long time ago.
There was a display cabinet in the apprentice training section full of exhibits, drill bits with hair wrapped round complete with a piece of scalp, tools with bits of finger stuck to them or covered in blood, etc. Just to remind us to take safety seriously.
Not directly related to guitar building but still about safety....
I do a lot of car restoration and always wear leather work gloves, there is nothing like rusty metal for carving your hands up, plus it makes them a lot easier to wash. Freshly cut metal can be razor sharpe. I once foolishly decide it was not worth putting my gloves on to 'just grind this bit off'. The grinder slipped and took off half the callous on my right hand index finger down to flesh. Very sore for months especially when I played.
I wear all the protective clothing, ear defenders, respirator, and face mask when grinding, even though at times it is hot and restricting. Steel toecap boots, fire proof overalls (I saw a college's overalls catch fire while he was welding and he did not realise until we shouted to him). Baseball cap on backwards to stop weld splatter going down my neck. Baseball cap on forwards when working under a car on the lift, to stop grit dropping behind my glasses and into my eyes.
I still manage to get minor injuries despite all my precautions but not as many as I would get otherwise.
I agree, always have a phone handy, especially if you are working on your own. I was in the loft above my garage and accidentally knocked the ladder down. I had my phone in my pocket and was able to ring my neighbour who came round and put it back up for me. I have since modified it so it cannot happen again.