Define high volume. Sorry, to be such a tard on the subject...
Heh... no problem. As you turn up the volume, your amp will pump out more power. "High volume" in this case is "loud" in the general sense - practicing with your band, playing at a gig, etc. (practicing alone is another matter, unless your neighbors don't mind you cranking your amp

).
I might've mentioned this before (I know I've mentioned it to lots of people), but RMS values are somewhat like "averages". Some people think that your amp delivers all of the power it says it does, all the time. But that's not the case.
Power rises and falls above the RMS rating at high volumes. At low volumes, you don't reach the RMS rating. At really low volumes, you're barely using any power at all, and at really high volumes, you approach the upper limits of what your amp can produce (which is MUCH more than the RMS rating).
So... playing at high volumes means using more of the power your amp was designed to deliver. Be mindful of how you decide to set up your cab with the 2001RB, because as your volume goes up, so does the power delivered to the speakers... and since that 15" speaker isn't rated very high, it probably won't handle what the 2001RB will deliver at a high volume (it'll be fine at low volumes, though).
Generally speaking, speakers need a certain amount of power to maximize their performance (the RMS power rating is a guideline). Going well above the RMS rating won't get you any more out of the speaker - unless farty distortion and more blown speakers are what you're looking for.
To muddy the waters a bit more... the RMS and peak power ratings of any cab don't necessarily correlate with the volume they can deliver. The one thing RMS is fairly useful for, though, is helping you to avoid blowing a speaker by better understanding what your gear can handle and deliver in a relative sense.
I'm pretty sure all your questions have been taken care of, but i thought i'd add that i play through a GK Avatar combination. I have the GK 700rbII and the 410 and 212 neo avatar cabs in matching red tolex and i couldn't be happier. I got the head off of here from a nice gent, and picked up the 410 about fifty bones less because it was supposedly scuffed. It delivers a REAL fat bottom end and plenty of control to cut through with crystal clear mids and hi's thanks to the bi amping capabilities. I've got tons of head room with the head, and its only the 700 model. lots of the guys on here use the 10001 and the 2001.
and it just looks sooooooooo hawtdamn sexy...
Ah... did you have your Avatars modified for GK bi-amping?