As far as the tube assignments you have this right. As for the lower gain tube in V2 - I'm not sure what you mean by less scooped. Let me explain what I have done, and why. Maybe it will make some sense, maybe not?
First off, Red Planet originally suggested that I try an RCA5814A tube in V1. I can't remember offhand what sonic benefits he claimed would occur, but I feel that tube offers tighter bass. I found a good deal and bought two so that I would have a backup tube. One of the reasons I wanted a low gain tube in V1 is that I wanted to be able to turn up the control on the input volume to the 12:00 position - I couldn't get much past 9:00 with the stock JJ tube. Also, I am not the least bit interested in overdrive, so the 5814A tube suits me to a tee.
Now to me, the STL900 seems to have a ton of bass. It fills out a small cab (single 10", single 12", small 210) better than any amp I've ever encountered. With a bigger cab there is way more than plenty, so I was hoping that yet another 5814A would flatten the response, and tighten the bass up even a bit more. Mission accomplished it seems, there is still lots of punchy bass, and more than enough treble gain to effectively EQ.
For me, the ultimate magic in this amp is the Mid EQ. I find that the the selector switch and level system is powerful, but takes a little getting used to. As well, the mids seem to really go a long way in defining how this amp sounds. I played with a lot of old and new tubes in V3, and have settled on two particular tubes for the moment. For a more punchy and lively tone, I use a JAN Phillips 12ax7 from the 80's. If I want a rounder, more "classic" tone, I use an older (60's I think) Sylvania long plate 12ax7.
With the tubes set up in this way, I'm starting to get a handle on how the 3 volume controls work. Turning up the input gain gives a rounder, "bassier" sound to the amp. The volume control gives more of a brighter, aggressive sound, while the master seems to increase volume while slightly compressing the sound. The 3 volume controls can be used as a type of auxiliary tone shaping, though using the 3 in conjunction takes a little getting used to.
I agree with Red Planet, this amp may not be fully understood yet in terms of how clever the design is, or how much potential there is to fine tune it for maximum tonal performance. Obviously, this sort of tweaking is not everybody's thing, but for those who like to fiddle a bit, some very worthwhile results can be achieved.