Pre eq is just that, the sound of the bass not colored by effects or the amp eq. In theory this will make his job easier, as he doesn't have to fight with a colored sound. right or wrong, it does have its place at times. It's usually done via the bass signal to a direct box, then the signal goes to the amp, where the bass rig is just a monitor for the bassist and does not have any input into the foh (front of house) sound.
Post eq is a signal, either from the amps direct line out, or from a mic on the cab, that takes the sound the bassist is getting from his rig and is used in the house mix.
The best in my opinion, is when a mix of a direct signal and a mic on the cab is used. The direct signal can tighten or notes, while the mic'd cab holds the body of the sound, adding the color of the combination of bass, effects, amp, and cab.