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String makers say,Hex Core are stiffer, and sound a little deeper. Round Core are more flexable and brighter. I can't really hear much difference in sound,but to me Round Core strings do feel more flexable. Hope this helps answer your question.
Yeah,they feel like they have a little more tension to me. Most strings are Hex Core. Some Round Core strings I have tried are,DR Sunbeams,DR Highbeams,Fender 8255's and Fender 8250's. The Fender 8250's have a tapered E & B string though,so I don't think you would want to use them unless your bass strings through the body.
I hexagonal core is considered by many to be better because the corners dig into the wrap wire creating a tighter and more stable wrap. Here is what D'Addario has to say about it:
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