Again, the question is a bit unanswerable. If you want more punch, which typically means more midrange, and you are not driving your current 410 cab or amp to the edge, adding another similar cab is not a very efficient way to get where you want to go.
If the OP said that his rig was running out of gas, or that he wanted to be louder, that is one thing... but adding a 210 to significantly increase mid punch makes little sense to me.
I guess one way to look at it is that the top 210's will be closer to the OP's ears, and he will get the 'impression' of more mid punch, but that isn't the same thing.
EQ, a change of technic, or finding a single cab that fits your tone goals would be the solution of choice for me. IMO there
That being said, running an 4ohm 410 and an 8ohm 210 with a head that is 2ohm capable is a wonderful thing... a modular 610, and you basically have given your self three rigs (assuming you have a solid state head that can handle the 2.67 ohm nominal impedance).... an 8ohm 210 at the lowest wattage for small gigs, a 4ohm 410 for most gigs at a higher wattage, and a 2.67ohm 610 for the big wumpin'... with each driver in all combinations seeing pretty much the same power in all three situations.
So, great idea in general, but possibly not to get the result I understand you are trying to achieve. IMO!