@beans-on-toast would it be ok to "daisy-chain" the cabs plugging into the 4 ohm speaker out?
It is best that the total daisy chained cabinet impedance matches whatever tap is used.
The 4 ohm jacks on the back of the chassis are internally connected in parallel. Plugging in two 8 ohm cabinets, one into each jack is the same as daisy chaining two 8 ohm cabsand using one jack.
In the case of a 4 ohm and an 8 ohm cab, daisy chained, the total impedance would be 2.7 ohms. This is a mismatch for this amp and Ampeg does not recommend doing this.
People do run their amps with mismatches and would argue as to which is best to use, the 2 ohm tap or the 4 ohm tap. I wouldn't recommend either. But if it were done, using the 4 ohm tap would be best. This would be at the expense of running the tubes down faster and more heat in the output transformer which could damage it long term. What you can get away with also depends on how hard the amp is driven. There are always tradeoffs and risks when you want to go against the manufacture's recommendations.
Chances are, the speaker cabs will not perform the same which would result in one being louder. It depends on the speakers and cab design. It would have to be tried to see.