What you may be taking about that you don't get in a modern amp - unless they design it into the circuitry - are some of the things that make a tube amp sound the way it does. There's natural compression, slower transient response, and different note bloom that's a natural consequence of the limitations of tube technology. And that has an effect on the sound. Some people hear that as rounder or smoother. It's a sound I also happen to prefer even though it's considered "old school" in some quarters.