The problem in dc coupling is at startup the grid will be at huge B+ rail potential, whilst the cathode will be at 0 potential as time the tubes are not heated. Such of high voltage diference (450 -500v) between grid and cathode can provide arcing, special in low u triode as 12at7, 12au7 where the grid are physically close spaced to cathode. When tubes are heated and start to conduct the plate voltage of driver tube will go down whilst the cathode voltage of the drived tube will go up resulting few volt difference between grid and cathode quite enough to bias the tube. A diode between grid and cathode will be quite enough to keep the voltage between g and k to a value low enough to be safe when the tubes not conduct (meant not warmed).The same author recommend a neon lamp to be used instead a diode which work as good as well. When the tubes will start to conduct will be out of the circuit. Extremely smart protection.I've designed DC coupled cathode followers, and there's no difference in sound from the diode, because the cathode is swinging up and down along with the grid from the input signal. As you say, the diode is there to prevent the tube's grid from momentarily going positive on power-up, and degrading tube life.
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