Typically a 4 wire humbucker pickup will have two wires for each coil - a start and a finish for each. The typical default option for most such pickups is to run the two coils in series - to do so, you put the start of one pickup at ground, connect the finish wires of the two pickups (and leave then floating, ie not connected to anything else), and the use the start wire if the second coil as hot.
A S-D pickup has black and white as one coil and red and green as the second coil. So the typical series arrangement is green as ground, red and white connected together, and black as hot. Here's a reference:
Humbucker Wire Color Translation - Guitar Pickups, Bass Pickups, Pedals
If your red and white wires are connected together, and not connected to anything else, it sounds like you have a typical series humbucker arrangement.