Snakes evolved from some kind of lizard about 150 million years ago (late Cretaceous-early Jurassic). I don't think they had to worry too much about cave men back then (well, Alley Oop, maybe..). Snakes that rely on their venom to kill prey can't afford to waste it on things they can't eat - like clumsy humans. But, since they have no legs or claws, hiding or biting you is their only defense; although garter snakes will pee on you...
. So it makes good evolutionary sense to have a warning system to try and scare you off. A lot of vipers - like rattlesnakes - can actually control their venom system to the point that they can bite you without injecting anything - but I wouldn't count on it. Personally, I think it's kind of sad to kill a snake that big. It took a long time for a rattler to grow that size; now it's dead, and for what? A selfie..

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