When shutting down it makes no difference if you go straight to switch off without first switching to standby. I think most people, including me, have just got into the habit of using standby when switching in both directions (or or off).
Likewise, pulling the IEC plug out before switching off won't harm the amp and some people claim that's actually a good idea because it is said to bleed the large power supply capacitors more quickly. I dunno about that. It seems to me that could be useful if one were planning on poking around inside the amp but otherwise it's probably irrelevant.
It a good habit to help be sure the amp is in standby before powering it up again next time/later.
I've always also had a habit with tube Ampegs I've owned to switch to standby, pause for at least a moment, if not a minute or two, then power off.
Being in rush to go somewhere else or do something else and playing bass, especially with a big tube amp, don't typically or naturally go hand in hand. If I'm that busy with other tasks I'm probably not also juggling noodling on a bass between things.
Playing out, same.
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