Old strings don't die, they just play that way...
Seriously tho... the molecules of most shaped and/formed metals, including bass strings, are bonded into crystallattice structures that determines their resiliency and tone. These structures deteriorate with each deformation applied to them.
Deformations may be caused in varying amounts by a variety of different manipulations.... which can come from contraction and/or expansion via temperature changes (faster/bigger changes are harder on strings, another good reason for acclimation periods), rapid/repeated changes in tension (I don't care to re-use bass strings), conduction of electrical current (thankfully not common with bass strings), corrosion or other chemical reactions (wash your grubby mitts and keep your bass clean), physical manipulations and movements (the harder you play, the faster the deterioration accumulates), and several other sources.
The deterioration is cumulative, and eventually causes the strings' abilities to produce desirable tones, stay in tune, play at a desired tension, and not break altogether, to fall below levels acceptable to the player and/or below their physical limits.
And this is why strings die.
Now we are getting somewhere! What you have not covered is the gradual uncoiling or slipping of the string wind structure.
as i see it, we have “metal fatigue and similar” as you describe. We then have gradual loosening of the coil wire/core wire structure (due to metal fatigue and stretching/deformation over time)… and we have dirt/corrosion. Then we have physical damage/abuse.
I think a brand new string that sounds “dead” is likely a slipped internal core, or a defect in the core or coiled wire (i am sure i am abusing and misusing terms and expect to soon be corrected).
I am still not sure as to why these strings can buzz (not nut or fret or saddle buzz) but i assume it has to do with changes in the internal core and or external wire wrap and how they interact to produce a desired tone.
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