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Best riff in a song

Heart of the Sunrise - Yes

Tom Sawyer - Rush

Carry on Wayward Son Intro/theme - Kansas

Out On the Tiles - Zeppelin

Run To The Hills - Iron Maiden

Number of the Beast - Iron Maiden

Breakin The Law - Judas Priest

Mayor Of Simpleton - XTC
 
My first inclination is to answer Sweet Child o Mine. I love that song and love that album.

On second thought, I thought I'd mention the riff that got me into playing bass... Anthrax - Caught in a Mosh.

Finally, I'll answer with something that makes me want to scream "F*(K YEAH!" every time I hear it... Intro to High on Fire - Snakes for the Divine. If I were ever a fighter, that would be my walkout music.

https://www.youtube.com/watch?v=9gtMadYA200
 
Out of left field I come and say that this is one of the great guitars riffs of at the VERY least punk history, from unfortunately still rather obscure band (and song) The riff at the beginning and throughout the verses I mean (the vocals end up pretty much following it):

https://www.youtube.com/watch?v=kXVhh7TKgcA


When I first heard it I had to go and pick my guitar to figure it out.

The guitarist is of course Stuart Adamson who would later form Big Country.


Another great riff from a more famous song:

https://www.youtube.com/watch?v=8I8mWG6HlmU

If you can stand Ian Astbury. I know personally I find it hard.
 
Kick Out the Jams - MC5 It's simple but it slays.
Working Man - Rush
54-46 Was My Number - Toots and the Maytals
Bed's Too Big Without You - Police or the Reggae Sunsplash 81 version (Sheila Hylton?)
Man there are a million
Fairies Wear Boots - Sabbath
Rockability - Brian Setzer (Go find it if you haven't heard it. I love that song.)