In addition to changing the pots you should also consider changing the tone capacitor.
The value of the tone capacitor is meaningless with the tone control at full. You can literally use a capacitor with 1000 times the normal value, and it'll sound the same. If you want to change what it sounds like when the tone pot is at minimum, then by all means change the tone cap, but as the OP wants more brightness, I'm assuming he's got the tone control dimed.
Here's a plot of a circuit simulation: It's a G&L MFD P pickup (similar in impedance to most P pickups), and it's loaded with a volume control , tone circuit, a cable, and a 1 Meg input impedance amplifier. The green curve is the stock circuit - .047 uF cap. The red circuit is with a 47 uF cap - 1000 times bigger. Most of what you see is red - that's because the red curve lies exactly on top of the green curve.
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