I'm with you 100% that the next generation ought to have a "pre/post" switch for the DI.
That said, I understand completely why Quilter designed it the way they did: The BB800's Gain and Master controls interact to shape your tone. Hypothetically, if the XLR Out was after the Gain but before the Master, then you would not be able to get the full range of tones into front-of-house. By putting the XLR Out post-Master, they've assured that what you hear on stage will be what goes to the board (for better or worse).
Well......
This is how they all work.
The master "indirectly" affects tone by allowing to set your pregain to any saturation point, by then letting you run that saturation point at any volume (master volume). If your "master volume" is doing anything tonewise other than just setting your overall acoustic volume output, then you have a bad design.
I don't think the Quilter is doing this and some are just looking to read a little too much magic into the formula.
I'm sure their master volume, like overwhelmingly most, is simply a volume control after all the "magic" has taken place.
Placing the DI after it, rather than before it, was probably oversite more than anything ("Well...it looked good on paper..."), inviting more than a few "HEY!? What are you doing?!" from various sound guys towards the bassist that may have to change his stage volume on occasion.
It's not even about volume to the board/house as much as how your input gain is no longer optimal to the board without continual on the fly adjustment during performance. I've played for anywhere from 4 to 40,000 in my career. Trust me, top tier sound techs would not go for this and force you to use a separate DI box (many do anyway).
If that's going to be the case, why even have the built in DI?
Kind of moot anyway.
Quilter recognized the issue and is supposedly fixing it on the next generation, so, I will continue to wait.