In general, no, tubes do not reduce high end.Is there normally some high end loss with tubes? I have an Underground Accelerator & enjoy the tone I get from it but I notice that it does limit some of the higher frequencies from my instrument which in turn effects other pedals in my chain. Is this common?
That said, the UA is a bit darker than other preamps I use. (I run three with a custom switcher; UA, DW, SVPre). The DW is extremely bright by comparison. I tend to use the UA where a darker, less modern, vintage, (insert fav descriptor of old school tone) is most appropriate. I let the skinny-stringers handle the high stuff; not my job. I've set it to give me a very touch sensitive breakup, that never gets 'grindy', just 'furry'.
The DW, by contrast, and in the manner in which I use it, gives me a modern, scooped tone with big big bottom, and glassy highs. I don't have much occasion to drive it into distortion, but it can do that well.
One last point: placement seems to matter quite a bit. In early experiments, it could sound very different, depending on what was in front of/behind it. I run all three very near the end of my chain, now, as I like being able to push the pre with various dirt/comp/boost pedals, rather than the other way 'round.
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Have to get all the yard work done while the weather is nice.